Product ID:MS-165 FREON TMS SOLVENT
MSDS Date:01/01/1986
FSC:6850
NIIN:00N009036
MSDS Number: BCRMQ

MILLER-STEPHENSON CHEMICAL CO.

GEORGE WASHINGTON HIGHWAY
DANBURY, CT 06810

Emergency Phone: 800-424-9300

Info Phone: 203-743-4447

Cage: 18598

MILLER-STEPHENSON CHEMICAL CO INC

950 DANBURY, CT 06810 US

Telephone: 203-743-4447

Cage: 18598

NITROMETHANE

CAS: 75-52-5

RTECS: PA9800000

Fraction By Weight: <1%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM; 9192

METHYL ALCOHOL (METHANOL) (SARA III)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 5%

OSHA PEL S,200PPM/250STEL

ACGIH TLV: S,200PPM/250STEL; 93

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 75%

OSHA PEL 1000PPM/1250STEL

ACGIH TLV: 1000PPM/1250STEL9192

DICHLORODIFLUOROMETHANE (SARA III)

CAS: 75-71-8

RTECS: PA8200000

Fraction By Weight: 20%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM; 9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:N/K
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:IN SCREENING TESTS WITH EXPERIMENTAL
ANIMALS,EXPOSURE AT APPROXIMATELY 500 PPM (V/V) AND ABOVE,FOLLOWED
BY A LARGE INTRAVENOUS EPINEPHRONE CHALLANGE,HAS INDUCED SERIOUS
CARDIAC IRREGULARITIES.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES:LIQ CONTACT CAN CAUSE IRRIT,SOLVENT
CONTAINS METHANOL.SKIN:METHANOL IS A SKIN IRRITANT.INGEST:N/K
.INHAL:VAP IS HEAVIER THAN AIR & CAN CAUSE SUFFOCIATION BY REDUCING
O*2 AVAIL FOR BRTH .HIGH CONC OF VAP MAY CAUSE
LIGHT-HEADNESS,GIDDINESS,SHORTNESS OF BRTH & MAY LEAD TO
NARCOSIS,CARD (SEE SUPP DATA)
Medical Cond Aggravated by Exposure:CARDIVASCULAR DISEASE
SUSCEPTIBILITY TO THE TOXICITY OF EXCESS EXPOSURE TO METHANOL.

First Aid:EYES:IMMED FLUSH W/ PLENTY OF H*2O FOR AT LEAST 15 MIN.CALL
MD.SKIN:FLUSH W/ H*2O.GET MED ATTN IF IRRIT IS PRESENT.INGEST:CALL
MD IMMED.INDUCE VOMITING TO LESSEN CHANCE OF VISION IMPAIRMENT.AS
AN ANTI DOTE,GIVE 100 ML OF 100 PROOF ETHYL ALCOHOL IN 2000 ML
H*2O.NEVER GIVE ANYTHING BY MOUYH TO AN UNCON PERSON.INHAL:REMOVE
TO FRESH AIR.GIVE ARTF RESP,PREFERABLY MOUTH TO MOUTH IF NEC.IF
BRTHG(SEE SUP)

Flash Point Method:TOC
Flash Point:NONE
Lower Limits:NONFLAMMABLE
Upper Limits:NONFLAMMABLE
Extinguishing Media:NONFLAMMABLE
Fire Fighting Procedures:WEAR PRESS DEMAND SCBA & FULL PROT EQUIP
.ADDITION OF EXCESS H*2O (>0.2%) WILL EXTRACT ALCOHOL AND FORM A
FLAMMABLE SUPERNATANT LIQUID LAYER.
Unusual Fire/Explosion Hazard:PRESSRUIZED AEROSOL CNTNR AT ELEVATED
TEMP MAY VENT,RUPTUE OR BRUST & ADD TO FLYING & FALLING
DEBRIS.DECOMP MAY OCCUR.HAZ DECOMP PROD:HCL.HF & 8SEE SUPP DATA.

Spill Release Procedures:VENTILATE/RELEASE ARE.REMOE OPEN FLAMES OR RED
HOT SURFACES.ALLOW TO EVAPORATE.
Neutralizing Agent:N/K

Handling and Storage Precautions:DO NOT STORE NEAR SOURCES OF
HEAT.INDIRECT SUNLIGHT OR WHERE TEMP EXCEED 120F,49C.DO NOT
PUNCTURE/DAMAGE CNTNRS.ROTATE STOCK TO SHELF LIFE OF ONE YR.
Other Precautions:NO SMOKING.DO NOT USE IN GEN VICIN ARC WELDING, OPEN
FLAME OR HOT SURFACES,HECHLORIDES,FLUORIDES OR PHOSGENE .AVOID
PRLNG SKIN EXPOS & BRTHG OF VAP.USE ONLY IN WELL VENTILATED AREAS

Respiratory Protection:NIOSH/MSHA APPROVED REWSPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .NONE REQUIRED UNDER MANUFACTURE CONDITION.SCBA
REQUIRED IF LARGE SPILL OCCURS.
Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR
CONCENTRATION BELOW TVL
Protective Gloves:NEOPRENE
Eye Protection:CHEMICAL WORKERS GOGGLES
Other Protective Equipment:N/K
Work Hygienic Practices:N/K
Supplemental Safety and Health
VP:429 MMHG & 77F.29.DEN:1.48 G/CC @ 77F,29C.VAP DENS:2.8 @ 77F,29C
(AIR=1).FIRE & EXPLO HAZ:POSSIBLE CARBONYL HALIDES FORM AT HIGH
TEMP.EFTS OF OVEREXPOS :IRREGULARITIES,UNCON OR DEATH,FIRST AID
PROC :IS DIFFICULT,GIVE O*2.DO NOT GIVE EPINEPHRINE OR SIMILAR
DRUGS.METHANOL:LD50 RAT ORAL 5628 MG/KG.

Boiling Pt:B.P. Text:103.3F.39C
Melt/Freeze Pt:M.P/F.P Text:N/
Vapor Pres:SEE SUPP
Vapor Density:SEE SUPP
Spec Gravity:N/K
pH:7
Evaporation Rate & Reference:(N-BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR,COLORLESS LIQUID,PAINT SOLVENT ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
ALKALI OR ALKALINE EARTH METALS (POWERD ALUMINUM,ZINC,BERYLLIUM,ETC).
Stability Condition to Avoid:AVOID SPRAYING NEAR OPEN FLAMES OR RED HOT
SURFACES.DO NOT HEAT AERSOL CONTAINERS ABOVE 120F.49C.
Hazardous Decomposition Products:HIGH TEMP (OPEN FLAME,GLOWING METAL
SURFACES,ETC) WILL DECOMP THIS CMPD FORMING HCL,HF AND POSSIBLE
CARBONYL HALIDES.
Conditions to Avoid Polymerization:WILL NOT OCCUR

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS . ALLOW TO EVAPORATE.DO NOT
PUNTURE OR INCINERATE AERSOL CANS.DISPOSAL SERVICE TO LANDFILL IS
APPROPRIATE.

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particular situation.